January 31, 2015

Perovskite top layer could boost solar to over 30% efficiency and cut overall costs in half

The power conversion efficiency of silicon photovoltaics has been stuck at 25 percent for 15 years but cheap tandem solar cells could affordably boost efficiency.

One cost-effective way to improve efficiency is to build a tandem device made of silicon and another inexpensive photovoltaic material, he said.

“Making low-cost tandems is very desirable,” McGehee said. “You simply put one solar cell on top of the other, and you get more efficiency than either could do by itself. From a commercial standpoint, it makes a lot of sense to use silicon for the bottom cell. Until recently, we didn’t have a good material for the top cell, then pervoskites came along.”

Perovskite is a crystalline material that is inexpensive and easy to produce in the lab. In 2009, scientists showed that perovskites made of lead, iodide and methylammonium could convert sunlight into electricity with an efficiency of 3.8 percent. Since then, researchers have achieved perovskite efficiencies above 20 percent, rivaling commercially available silicon solar cells and spawning widespread interest among silicon manufacturers.

When the Stanford group added perovskite to silicon solar cells whose efficiency was already 17 percent, for example, they measured a much smaller increase in power output, to 17.9 percent.

Even so, perovskites could be a boon for the solar industry. The researchers believe that perovskite-silicon cells will convert over 30 percent of the energy in sunlight into electricity. Such a boost would cut the number of solar panels for some installations almost in half, greatly lowering installation costs.

A key roadblock to building an efficient perovskite-silicon tandem has been a lack of transparency.

“Colin had to figure out how to put a transparent electrode on the top so that some photons could penetrate the perovskite layer and be absorbed by the silicon at the bottom,” McGehee said. “No one had ever made a perovskite solar cell with two transparent electrodes.”

Perovskites are easily damaged by heat and readily dissolve in water. This inherent instability ruled out virtually all of the conventional techniques for applying electrodes onto the perovoskite solar cell, so Bailie did it manually.

“We used a sheet of plastic with silver nanowires on it,” he said. “Then we built a tool that uses pressure to transfer the nanowires onto the perovskite cell, kind of like a temporary tattoo. You just need to rub it to transfer the film.”

For the experiment, the Stanford team stacked a perovskite solar cell with an efficiency of a 12.7 percent on top of a low-quality silicon cell with an efficiency of just 11.4 percent.

“We improved the 11.4 percent silicon cell to 17 percent as a tandem, a remarkable relative efficiency increase of nearly 50 percent,” McGehee said. “Such a drastic improvement in efficiency has the potential to redefine the commercial viability of low-quality silicon.”

In another experiment, the research team replaced the silicon solar cell with a cell made of copper indium gallium diselenide (CIGS). The researchers stacked a 12.7 percent efficiency perovskite cell onto a CIGS cell with a 17 percent efficiency. The resulting tandem achieved an overall conversion efficiency of 18.6 percent.

“Since most, if not all, of the layers in a perovskite cell can be deposited from solution, it might be possible to upgrade conventional solar cells into higher-performing tandems with little increase in cost,” the authors wrote.

A big unanswered question is the long-term stability of perovskites, McGehee added.

“Silicon is a rock,” he said. “You can heat it to about 600 degrees Fahrenheit shine light on it for 25 years and nothing will happen. But if you expose perovskite to water or light it likely will degrade. We have a ways to go to show that perovskite solar cells are stable enough to last 25 years. My vision is that some day we’ll be able to get low-cost tandems that are 25 percent efficient. That’s what companies are excited about. In five to 10 years, we could even reach 30 percent efficiency.”

SOURCES - Stanford, Technology Review

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