January 25, 2016

Rice University develops conductive graphene composite material to heat surfaces, simplify ice removal

A thin coating of graphene nanoribbons in epoxy developed at Rice University has proven effective at melting ice on a helicopter blade.

The coating by the Rice lab of chemist James Tour may be an effective real-time de-icer for aircraft, wind turbines, transmission lines and other surfaces exposed to winter weather, according to a new paper in the American Chemical Society journal ACS Applied Materials and Interfaces.

In tests, the lab melted centimeter-thick ice from a static helicopter rotor blade in a minus-4-degree Fahrenheit environment. When a small voltage was applied, the coating delivered electrothermal heat – called Joule heating – to the surface, which melted the ice.

The nanoribbons produced commercially by unzipping nanotubes, a process also invented at Rice, are highly conductive. Rather than trying to produce large sheets of expensive graphene, the lab determined years ago that nanoribbons in composites would interconnect and conduct electricity across the material with much lower loadings than traditionally needed.

Rice University scientists embedded graphene nanoribbon-infused epoxy in a section of helicopter blade to test its ability to remove ice through Joule heating. (Credit: Tour Group/Rice University)


Lab tests at Rice University on a section of a helicopter rotor chilled to minus-4 degrees Fahrenheit show that a thin coat of nanoribbon-infused epoxy can be used as a de-icer. The composite, imbedded between an abrasion shield and the blade in the sample above, heated when electricity was applied, melting the ice. The material may be suitable for keeping aircraft, wind turbines and transmission lines free of ice. (Credit: Tour Group/Rice University)

Applied Materials and Interfaces - Composites of Graphene Nanoribbon Stacks and Epoxy for Joule Heating and Deicing of Surfaces




Previous experiments showed how the nanoribbons in films could be used to de-ice radar domes and even glass, since the films can be transparent to the eye.

“Applying this composite to wings could save time and money at airports where the glycol-based chemicals now used to de-ice aircraft are also an environmental concern,” Tour said.

In Rice’s lab tests, nanoribbons were no more than 5 percent of the composite. The researchers led by Rice graduate student Abdul-Rahman Raji spread a thin coat of the composite on a segment of rotor blade supplied by a helicopter manufacturer; they then replaced the thermally conductive nickel abrasion sleeve used as a leading edge on rotor blades. They were able to heat the composite to more than 200 degrees Fahrenheit.

For wings or blades in motion, the thin layer of water that forms first between the heated composite and the surface should be enough to loosen ice and allow it to fall off without having to melt completely, Tour said.

The lab reported that the composite remained robust in temperatures up to nearly 600 degrees Fahrenheit.

As a bonus, Tour said, the coating may also help protect aircraft from lightning strikes and provide an extra layer of electromagnetic shielding.

Abstract

A conductive composite of graphene nanoribbon (GNR) stacks and epoxy is fabricated. The epoxy is filled with the GNR stacks, which serve as a conductive additive. The GNR stacks are on average 30 nm thick, 250 nm wide and 30 μm long. The GNR-filled epoxy composite exhibits a conductivity over 100 S/m at 5 wt% GNR content. This permits application of the GNR-epoxy composite for deicing of surfaces through Joule (voltage-induced) heating generated by the voltage across the composite. A power density of 0.5 W/cm2 was delivered to remove ~1-cm-thick (14 g) monolith of ice from a static helicopter rotor blade surface in a ̶ 20 °C environment.

SOURCES - Rice University, Applied Materials and Interfaces

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