The Rice labs of chemist James Tour and civil and environmental engineer Rouzbeh Shahsavari combined the nanoribbons with an oil-based thermoset polymer intended to make wells more stable and cut production costs. When cured in place with low-power microwaves emanating from the drill assembly, the composite would plug the microscopic fractures that allow drilling fluid to seep through and destabilize the walls.
ACS Applied Materials and Interfaces - Microwave Heating of Functionalized Graphene Nanoribbons in Thermoset Polymers for Wellbore Reinforcement
The researchers said that in the past, drillers have tried to plug fractures with mica, calcium carbonate, gilsonite and asphalt to little avail because the particles are too large and the method is not efficient enough to stabilize the wellbore.
In lab tests, a polymer-nanoribbon mixture was placed on a sandstone block, similar to the rock that is encountered in many wells. The team found that rapidly heating the graphene nanoribbons to more than 200 degrees Celsius with a 30-watt microwave was enough to cause crosslinking in the polymer that had infiltrated the sandstone, Tour said. The microwave energy needed is just a fraction of that typically used by a kitchen appliance, he said.
“This is a far more practical and cost-effective way to increase the stability of a well over a long period,” Tour said.
In the lab, the nanoribbons were functionalized — or modified — with polypropylene oxide to aid their dispersal in the polymer.
Mechanical tests on composite-reinforced sandstone showed the process increased its average strength from 5.8 to 13.3 megapascals, a 130 percent boost in this measurement of internal pressure, Shahsavari said. Similarly, the toughness of the composite increased by a factor of six.
“That indicates the composite can absorb about six times more energy before failure,” he said.
“Mechanical testing at smaller scales via nanoindentation exhibited even more local enhancement, mainly due to the strong interaction between nanoribbons and the polymer. This, combined with the filling effect of the nanoribbon-polymer into the pore spaces of the sandstone, led to the observed enhancements.”
The researchers suggested a low-power microwave attachment on the drill head would allow for in-well curing of the nanoribbon-polymer solution.
Here, we introduce a systematic strategy to prepare composite materials for wellbore reinforcement using graphene nanoribbons (GNRs) in a thermoset polymer irradiated by microwaves. We show that microwave absorption by GNRs functionalized with poly(propylene oxide) (PPO-GNRs) cured the composite by reaching 200 °C under 30 W of microwave power. Nanoscale PPO-GNRs diffuse deep inside porous sandstone and dramatically enhance the mechanics of the entire structure via effective reinforcement. The bulk and the local mechanical properties measured by compression and nanoindentation mechanical tests, respectively, reveal that microwave heating of PPO-GNRs and direct polymeric curing are major reasons for this significant reinforcement effect.
SOURCES - Rice University, ACS Applied Materials and Interfaces