Ultra-thin quantum light emitting diodes (LEDs) – made of layered materials just a few atoms thick – have been developed by researchers at the University of Cambridge. Constructed of layers of different ultra-thin materials, the devices could be used in the development of new computing and sensing technologies. The ability to produce single photons using only electrical current is an important step towards building quantum networks on compact chips.
The devices are constructed of thin layers of different materials stacked together: graphene, boron nitride and transition metal dichalcogenides (TMDs). The TMD layer contains regions where electrons and electron vacancies, or holes, are tightly confined. When an electron fills an electron vacancy that sits at a lower energy than the electron, the energy difference is released as a photon, a particle of light. In the LED devices, a voltage pushes electrons through the device, where they fill the holes and emit single photons.
A computer built on the principles of quantum mechanics would be both far more powerful and more secure than current technologies, and would be capable of performing calculations that cannot be performed otherwise. However, in order to make such a device possible, researchers need to develop reliable methods of electrically generating single, indistinguishable photons as carriers of information across quantum networks.
Nature Communications - Atomically thin quantum light-emitting diodes
The ultra-thin platform developed by the Cambridge researchers offers high levels of tunability, design freedom, and integration capabilities. Typically, single photon generation requires large-scale optical set-ups with several lasers and precise alignment of optical components. This new research brings on-chip single photon emission for quantum communication a step closer. The results are reported in the journal Nature Communications.
“Ultimately, we need fully integrated devices that we can control by electrical impulses, instead of a laser that focuses on different segments of an integrated circuit,” said Professor Mete Atatüre of Cambridge’s Cavendish Laboratory, one of the paper’s senior authors. “For quantum communication with single photons, and quantum networks between different nodes, we want to be able to just drive current and get light out. There are many emitters that are optically excitable, but only a handful are electrically driven.”
The layered nature of TMDs makes them ideal for use in ultra-thin structures on chips. They also offer an advantage over some other single-photon emitters for feasible and effective integration into nanophotonic circuits.
With this research, quantum emitters are now seen in another TMD material, namely tungsten disulphide (WS2). “We chose WS2 because we wanted to see if different materials offered different parts of the spectra for single photon emission,” said Atatüre, who is a Fellow of St John's College. “With this, we have shown that the quantum emission is not a unique feature of WS2, which suggests that many other layered materials might be able to host quantum dot-like features as well.”
“We are just scratching the surface of the many possible applications of devices prepared by combining graphene with other materials,” said senior co-author Professor Andrea Ferrari, Director of the Cambridge Graphene. “In this case, not only have we demonstrated controllable photon sources, but we have also shown that the field of quantum technologies can greatly benefit from layered materials. Many more exciting results and applications will surely follow.”
Transition metal dichalcogenides are optically active, layered materials promising for fast optoelectronics and on-chip photonics. We demonstrate electrically driven single-photon emission from localized sites in tungsten diselenide and tungsten disulphide. To achieve this, we fabricate a light-emitting diode structure comprising single-layer graphene, thin hexagonal boron nitride and transition metal dichalcogenide mono- and bi-layers. Photon correlation measurements are used to confirm the single-photon nature of the spectrally sharp emission. These results present the transition metal dichalcogenide family as a platform for hybrid, broadband, atomically precise quantum photonics devices.
Incorporating single-photon sources into optoelectronic circuits is a key challenge to develop scalable quantum-photonic technologies. Despite a plethora of single-photon sources reported to-date, all-electrical operation, desired for systems integration, is reported for only a few. Layered materials (LMs) offer novel opportunities for next-generation photonic and optoelectronic technologies such as lasers modulators and photodetectors and are compatible with the silicon platform.
The attractiveness of single-photon sources in LMs stems from their ability to operate at the fundamental limit of few-atom thickness, providing the potential to integrate into conventional and scalable high-speed optoelectronic systems. Transition metal dichalcogenides (TMDs), being optically active layered semiconductors, are particularly suitable for developing quantum-light generating devices.
Here we demonstrate that LMs enable all-electrical single-photon generation over a broad spectrum. We use a light-emitting diode (LED) realized by vertical stacking of LMs and achieve charge injection into the active layer containing quantum emitters. We show that quantum emitters in tungsten diselenide (WSe2) can operate electrically. We further report all-electrical single-photon generation in the visible spectrum from a new class of quantum emitters in tungsten disulfide (WS2). Our results highlight the promise of LMs as a new platform for broadband hybrid all-integrated quantum-photonic circuits.
SOURCES - Nature Communications, Cambridge University