February 02, 2017

Rewritable Paper that uses light and no ink

Developing efficient photoreversible color switching systems for constructing rewritable paper is of significant practical interest owing to the potential environmental benefits including forest conservation, pollution reduction, and resource sustainability. Here we report that the color change associated with the redox chemistry of nanoparticles of Prussian blue and its analogues could be integrated with the photocatalytic activity of TiO2 nanoparticles to construct a class of new photoreversible color switching systems, which can be conveniently utilized for fabricating ink-free, light printable rewritable paper with various working colors. The current system also addresses the phase separation issue of the previous organic dye-based color switching system so that it can be conveniently applied to the surface of conventional paper to produce an ink-free light printable rewritable paper that has the same feel and appearance as the conventional paper. With its additional advantages such as excellent scalability and outstanding rewriting performance (reversibility over 80 times, legible time over 5 days, and resolution over 5 μm), this novel system can serve as an eco-friendly alternative to regular paper in meeting the increasing global needs for environment protection and resource sustainability.

Currently, paper production and disposal have a large negative impact on the environment: paper production is a leading source of industrial pollution, discarded paper is a major component (approximately 40%) of landfills, and even recycling paper contributes to pollution due to the process of ink removal. There is also the issue of deforestation: in the US, about one-third of all harvested trees are used for paper and cardboard production.

Working to address these problems, researchers have been investigating alternatives to disposable paper. One possibility is to take advantage of the color-switching ability of certain chemicals when exposed to light, although in the past this approach has faced challenges in terms of stability, limited reversibility, high cost, toxicity, and difficulty in applying the coating to ordinary porous paper.

Nanoletters - Photocatalytic Color Switching of Transition Metal Hexacyanometalate Nanoparticles for High-Performance Light-Printable Rewritable Paper

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