Science and Technology of Advanced Materials – Atomic switches: atomic-movement-controlled nanodevices for new types of computing It is a review of new types of nanodevices and computing based on cationic-based atomic switches. The researchers describe the fundamental mechanisms governing the operation of nanoionic atomic switches with detailed examples of their own three terminal devices, and predict a bright future for integrating atomic switches with conventional silicon devices by using ionic conductive materials.
Atomic switches are nanoionic devices that control the diffusion of metal cations and their reduction/oxidation processes in the switching operation to form/annihilate a metal atomic bridge, which is a conductive path between two electrodes in the on-state. In contrast to conventional semiconductor devices, atomic switches can provide a highly conductive channel even if their size is of nanometer order. In addition to their small size and low on-resistance, their nonvolatility has enabled the development of new types of programmable devices, which may achieve all the required functions on a single chip. Three-terminal atomic switches have also been developed, in which the formation and annihilation of a metal atomic bridge between a source electrode and a drain electrode are controlled by a third (gate) electrode. Three-terminal atomic switches are expected to enhance the development of new types of logic circuits, such as nonvolatile logic. The recent development of atomic switches that use a metal oxide as the ionic conductive material has enabled the integration of atomic switches with complementary metal-oxide-semiconductor (CMOS) devices, which will facilitate the commercialization of atomic switches. The novel characteristics of atomic switches, such as their learning and photosensing abilities, are also introduced in the latter part of this review.
In its simplest configuration, the operation of a nanoionic atomic switch consists of the formation and disintegration of nanometer sized metallic wires via a solid electrochemical reaction, which leads to major changes in the resistance between electrodes—the ‘on’ and ‘off’ states.
In this review, Hino and colleagues describe the control of silver ions in silver sulphide—an ionic conductor— using an STM tip to inject electrons to produce silver protrusions on the surface of silver sulphide, and their shrinkage by applying an appropriate bias voltage between the STM tip and electrode. Importantly, the application of a positive bias between a silver sulphide tip and a platinum surface leads to the growth of silver wires and a negative bias led their shrinkage. This bipolar control is important for practical device applications.
Gap-type atomic switches are a fundamental building block for bipolar nanoionic devices. Here, the researchers give a detailed account of bipolar switching using silver sulphide STM tips and platinum electrodes based on their own experiments on ‘crossbar’ device structures with a 1 nm gap between silver sulphide and platinum, with emphasis on the physical mechanism governing high speed switching at 1 MHz, and the finding that switching time decreases exponentially with increasing bias voltage. The authors stress that the development of a reproducible method for fabricating ‘crossbar’ devices was a major breakthrough, which enabled the first demonstration of nanoionic circuits such as logic gates.
With a view to practical applications of atomic switches, the authors give examples of advanced atomic switches including gapless-type devices consisting of metal/ionic conductor/metal structures, where one of the metals is electrochemically active and the other inert. Notably, recent reports on the use of metal oxides as ionic conductors have added further momentum for device commercialization.
Notably, gapless atomic switches also act as so-called ‘memristors’ (memory resistors)—passive two terminal multi-state memory devices—where the size of the nanowire protrusion governs the operation characteristics.
Other advanced atomic switches include: three terminal devices such as structures with a solid copper sulphide electrolyte, where the formation of a copper bridge between a platinum-source electrode and copper-drain electrode is controlled by a copper gate-electrode; and photoassisted atomic switches, which do not require nanogaps, and nanowire protrusions are grown by optical irradiation of a photoconductive material located between the anion and electron conducting electrode and a counter metal electrode. Intriguingly, since the switch is turned ‘on’ when the growing metal protrusion reaches the counter electrode, and the protrusion does not grow in the dark, the photoassisted atomic switch behaves as a programmable switch that could be used in erasable programmable read-only memory (EPROM).
The authors also describe the ‘learning abilities’ of atomic switches capable of short-term and long-term memories in single nanoionic devices; nonvolatile bipolar switches; two terminal atomic switch logic gates; and field programmable gate arrays integrated with CMOS devices.
This review contains 77 references and 20 figures and provides an invaluable source of up-to-date information for newcomers and experts in this exciting area of research.
We demonstrate a conceptually new atom transistor operation by electric-field control of the nanoionic state. The new atom transistor possesses novel characteristics, such as dual functionality of selective volatile and nonvolatile operations, very small power consumption (pW), and a high ON/OFF ratio [10^6 (volatile operation) to 10^8 (nonvolatile operation)], in addition to complementary metal oxide semiconductor (CMOS) process compatibility enabling the development of future computing systems that fully utilize highly-integrated CMOS technology. Cyclic endurance of 10^4 times switching was achieved with the prototype
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