Graphene grains come in several different shapes. Hydrogen gas controls the grains’ appearance.
A new approach to growing graphene greatly reduces problems that have plagued researchers in the past and clears a path to the crystalline form of graphite’s use in sophisticated electronic devices of tomorrow.
Findings of researchers at the Department of Energy’s Oak Ridge National Laboratory demonstrate that hydrogen rather than carbon dictates the graphene grain shape and size.
We show that graphene chemical vapor deposition growth on copper foil using methane as a carbon source is strongly affected by hydrogen, which appears to serve a dual role: an activator of the surface bound carbon that is necessary for monolayer growth and an etching reagent that controls the size and morphology of the graphene domains. The resulting growth rate for a fixed methane partial pressure has a maximum at hydrogen partial pressures 200–400 times that of methane. The morphology and size of the graphene domains, as well as the number of layers, change with hydrogen pressure from irregularly shaped incomplete bilayers to well-defined perfect single layer hexagons. Raman spectra suggest the zigzag termination in the hexagons as more stable than the armchair edges.
“Hydrogen not only initiates the graphene growth, but controls the graphene shape and size,” Vlassiouk said. “In our paper, we have described a method to grow well-defined graphene grains that have perfect hexagonal shapes pointing to the faultless single crystal structure.”
In the past two years, graphene growth has involved the decomposition of carbon-containing gases such as methane on a copper foil under high temperatures, the so-called chemical vapor deposition method. Little was known about the exact process, but researchers knew they would have to gain a better understanding of the growth mechanism before they could produce high-quality graphene films.
Until now, grown graphene films have consisted of irregular- shaped graphene grains of different sizes, which were usually not single crystals.
“We have shown that, surprisingly, it is not only the carbon source and the substrate that dictate the growth rate, the shape and size of the graphene grain,” Vlassiouk said. “We found that hydrogen, which was thought to play a rather passive role, is crucial for graphene growth as well. It contributes to both the activation of adsorbed molecules that initiate the growth of graphene and to the elimination of weak bonds at the grain edges that control the quality of the graphene.”
Using their new recipe, Vlassiouk and colleagues have created a way to reliably synthesize graphene on a large scale. The fact that their technique allows them to control grain size and boundaries may result in improved functionality of the material in transistors, semiconductors and potentially hundreds of electronic devices.
Implications of this research are significant, according to Vlassiouk, who said, “Our findings are crucial for developing a method for growing ultra-large-scale single domain graphene that will constitute a major breakthrough toward graphene implementation in real-world devices.”
Brian Wang is a Futurist Thought Leader and a popular Science blogger with 1 million readers per month. His blog Nextbigfuture.com is ranked #1 Science News Blog. It covers many disruptive technology and trends including Space, Robotics, Artificial Intelligence, Medicine, Anti-aging Biotechnology, and Nanotechnology.
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