Integrating a complex, single-crystal material with “giant” piezoelectric properties onto silicon, University of Wisconsin-Madison engineers and physicists can fabricate low-voltage, near-nanoscale electromechanical devices that could lead to improvements in high-resolution 3-D imaging, signal processing, communications, energy harvesting, sensing, and actuators for nanopositioning devices, among others.
The utility of ferroelectric materials stems from the ability to nucleate and move polarized domains using an electric field. To understand the mechanisms of polarization switching, structural characterization at the nanoscale is required. We used aberration-corrected transmission electron microscopy to follow the kinetics and dynamics of ferroelectric switching at millisecond temporal and subangstrom spatial resolution in an epitaxial bilayer of an antiferromagnetic ferroelectric (BiFeO3) on a ferromagnetic electrode (La0.7Sr0.3MnO3). We observed localized nucleation events at the electrode interface, domain wall pinning on point defects, and the formation of ferroelectric domains localized to the ferroelectric and ferromagnetic interface. These results show how defects and interfaces impede full ferroelectric switching of a thin film.
Piezoelectric materials use mechanical motion to generate an electrical signal, such as the light that flashes in some children’s shoe heels when they stomp their feet. Conversely, piezoelectrics also can use an electrical signal to generate mechanical motion-for example, piezoelectric materials are used to generate high-frequency acoustic waves for ultrasound imaging.
Eom studies the advanced piezoelectric material lead magnesium niobate-lead titanate, or PMN-PT. Such materials exhibit a “giant” piezoelectric response that can deliver much greater mechanical displacement with the same amount of electric field as traditional piezoelectric materials. They also can act as both actuators and sensors. For example, they use electricity to deliver an ultrasound wave that penetrates deeply into the body and returns data capable of displaying a high-quality 3-D image.
Currently, a major limitation of these advanced materials is that to incorporate them into very small-scale devices, researchers start with a bulk material and grind, cut and polish it to the size they desire. It’s an imprecise, error-prone process that’s intrinsically ill-suited for nanoelectromechanical systems (NEMS) or microelectromechanical systems (MEMS).
Until now, the complexity of PMN-PT has thwarted researchers’ efforts to develop simple, reproducable microscale fabrication techniques.
Applying microscale fabrication techniques such as those used in computer electronics, Eom’s team has overcome that barrier. He and his colleagues worked from the ground up to integrate PMN-PT seamlessly onto silicon. Because of potential chemical reactions among the components, they layered materials and carefully planned the locations of individual atoms.
“You have to lay down the right element first,” says Eom.
Onto a silicon “platform,” his team adds a very thin layer of strontium titanate, which acts as a template and mimics the structure of silicon. Next comes a layer of strontium ruthenate, an electrode Eom developed some years ago, and finally, the single-crystal piezoelectric material PMN-PT.
The researchers have characterized the material’s piezoelectric response, which correlates with theoretical predictions.
“The properties of the single crystal we integrated on silicon are as good as the bulk single crystal,” says Eom.
His team calls devices fabricated from this giant piezoelectric material “hyper-active MEMS” for their potential to offer researchers a high level of active control. Using the material, his team also developed a process for fabricating piezoelectric MEMS.
Applied in signal processing, communications, medical imaging and nanopositioning actuators, hyperactive MEMS devices could reduce power consumption and increase actuator speed and sensor sensitivity. Additionally, through a process called energy harvesting, hyperactive MEMS devices could convert energy from sources such as mechanical vibrations into electricity that powers other small devices-for example, for wireless communication.
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