Spherical silicon nanoparticles with sizes of a few hundreds of nanometers represent a unique optical system. According to theoretical predictions based on Mie theory they can exhibit strong magnetic resonances in the visible spectral range. The basic mechanism of excitation of such modes inside the nanoparticles is very similar to that of split-ring resonators, but with one important difference that silicon nanoparticles have much smaller losses and are able to shift the magnetic resonance wavelength down to visible frequencies. We experimentally demonstrate for the first time that these nanoparticles have strong magnetic dipole resonance, which can be continuously tuned throughout the whole visible spectrum varying particle size and visually observed by means of dark-field optical microscopy. These optical systems open up new perspectives for fabrication of low-loss optical metamaterials and nanophotonic devices.
We experimentally demonstrate for the first time that spherical silicon nanoparticles with sizes in the range from 100 nm to 200 nm have strong magnetic dipole response in the visible spectral range. The scattered “magnetic” light by these nanoparticles is so strong that it can be easily seen under a dark-field optical microscope. The wavelength of this magnetic resonance can be tuned throughout the whole visible spectral range from violet to red by just changing the nanoparticle size.
Technology Review – Invisibility cloaks that work for microwaves are easy to make using simple building blocks. Now engineers have created the equivalent building blocks for visible light.
The building blocks of microwave cloaks are split ring resonators–c-shaped pieces of metal in which electric and magnetic fields resonate when they interact with a electromagnetic wave. This interaction is what steers microwaves in a way that cloaks objects
These split ring resonators need to be a little smaller than the wavelengths they are designed to interact with. For microwaves, that’s the centimetre scale and so are relatively easy to make and assemble.
But that’s much harder at optical wavelengths, where the scale is measured in nanometres..What’s more, losses become much more significant on this scale because most metals tend to absorb visible light rather than transmit it.
Consequently, nobody has been able to make split ring resonators that work for visible light. The optical cloaks made so far all rely on other structures such as gold nanorods or holes drilled through silicon slabs.)
So anybody who finds a way to create the optical version of split ring resonators might reasonably be said to be sitting on an important breakthrough.
Enter Arseniy Kuznetsov at the Data Storage Institute in Singapore and a few pals. These guys say they’ve found an alternative to split ring resonators that work well at optical frequencies, with few losses.
This alternative is silicon nanospheres between 100 and 200 nm in diameter. It turns out that these spheres behave just like split ring resonators in the sense that they allow for the same kind of magnetic resonances when they interact with light.
The trouble of course is making these spheres. Chemists have been making much smaller spheres–between 2nm and 50nm in diameter–for some time now using various self assembly techniques to grow tiny crystals or ‘quantum dots’ as they are called. (These are useful because they fluoresce at well defined and controllable wavelengths.)
To make larger spheres, Kuznetsov blast a slab of silicon with a short pulse of high-powered laser light. This evaporates the silicon which then condenses into liquid balls. These solidify into spheres as they fall back on to the surface as a kind of silicon rain.
The end result is a surface covered with solid silicon nanospheres between 100 and 200nm in diameter.
Kuznetsov calculated how the magnetic fields inside these balls should resonate when they are zapped with light and then used a hi-tec tweezer and magnifying set to see whether the behaviour matched the theory.
Turns out it does. This magnetic resonance can be tuned to match any part of the visible spectrum simply selecting spheres of a specific size.
That’s important because it opens up an entirely new way make invisibility cloaks that operate in the visible region. “These optical systems open up new perspectives for fabrication of low-loss optical metamaterials and nanophotonic devices,” they say.
That could have a significant impact on the way optical cloaks are designed and made.
There are plenty of challenges ahead, however. Not least of these will be finding a reliable way to make nanospheres of a specific size.
Then there is the problem of assembling nanospheres into useful devices in a way that scales. That’s not something that a tweezer and magnifying set can help with, no matter how hi-tec.
Brian Wang is a Futurist Thought Leader and a popular Science blogger with 1 million readers per month. His blog Nextbigfuture.com is ranked #1 Science News Blog. It covers many disruptive technology and trends including Space, Robotics, Artificial Intelligence, Medicine, Anti-aging Biotechnology, and Nanotechnology.
Known for identifying cutting edge technologies, he is currently a Co-Founder of a startup and fundraiser for high potential early-stage companies. He is the Head of Research for Allocations for deep technology investments and an Angel Investor at Space Angels.
A frequent speaker at corporations, he has been a TEDx speaker, a Singularity University speaker and guest at numerous interviews for radio and podcasts. He is open to public speaking and advising engagements.