Large Graphene Crystals Grown for super fast electronics in relative near term and potential for superstrong materials later

Texas researchers used surface oxygen to grow centimeter-size single graphene crystals on copper. The crystals were about 10,000 times as large as the largest crystals from only four years ago. Very large single crystals have exceptional electrical properties.

One of the world’s strongest materials, graphene is flexible and has high electrical and thermal conductivity that makes it a promising material for flexible electronics, solar cells, batteries and high-speed transistors. The team’s understanding of how graphene growth is influenced by differing amounts of surface oxygen is a major step toward improved high-quality graphene films at industrial scale.

The team’s method “is a fundamental breakthrough, which will lead to growth of high-quality and large area graphene film,” said Sanjay Banerjee, who heads the Cockrell School’s South West Academy of Nanoelectronics (SWAN). “By increasing the single-crystal domain sizes, the electronic transport properties will be dramatically improved and lead to new applications in flexible electronics.”

Graphene has always been grown in a polycrystalline form, that is, it is composed of many crystals that are joined together with irregular chemical bonding at the boundaries between crystals (“grain boundaries”), something like a patch-work quilt. Large single-crystal graphene is of great interest because the grain boundaries in polycrystalline material have defects, and eliminating such defects makes for a better material.

“In the long run it might be possible to achieve meter-length single crystals,” Ruoff said. “This has been possible with other materials, such as silicon and quartz. Even a centimeter crystal size — if the grain boundaries are not too defective — is extremely significant.”

“We can start to think of this material’s potential use in airplanes and in other structural applications — if it proves to be exceptionally strong at length scales like parts of an airplane wing, and so on,” he said.

Another major finding by the team was that the “carrier mobility” of electrons (how fast the electrons move) in graphene films grown in the presence of surface oxygen is exceptionally high. This is important because the speed at which the charge carriers move is important for many electronic devices — the higher the speed, the faster the device can perform.

Yufeng Hao says he thinks the knowledge gained in this study could prove useful to industry.

“The high quality of the graphene grown by our method will likely be developed further by industry, and that will eventually allow devices to be faster and more efficient,” Hao said.

Single-crystal films can also be used for the evaluation and development of new types of devices that call for a larger scale than could be achieved before, added Colombo.

“At this time, there are no other reported techniques that can provide high quality transferrable films,” Colombo said. “The material we were able to grow will be much more uniform in its properties than a polycrystalline film.”

The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper

The growth of high-quality single crystals of graphene by chemical vapor deposition on copper (Cu) has not always achieved control over domain size and morphology, and the results vary from lab to lab under presumably similar growth conditions. We discovered that oxygen (O) on the Cu surface substantially decreased the graphene nucleation density by passivating Cu surface active sites. Control of surface O enabled repeatable growth of centimeter-scale single-crystal graphene domains. Oxygen also accelerated graphene domain growth and shifted the growth kinetics from edge-attachment–limited to diffusion-limited. Correspondingly, the compact graphene domain shapes became dendritic. The electrical quality of the graphene films was equivalent to that of mechanically exfoliated graphene, in spite of being grown in the presence of O.

24 pages of supplemental material

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Large Graphene Crystals Grown for super fast electronics in relative near term and potential for superstrong materials later

Texas researchers used surface oxygen to grow centimeter-size single graphene crystals on copper. The crystals were about 10,000 times as large as the largest crystals from only four years ago. Very large single crystals have exceptional electrical properties.

One of the world’s strongest materials, graphene is flexible and has high electrical and thermal conductivity that makes it a promising material for flexible electronics, solar cells, batteries and high-speed transistors. The team’s understanding of how graphene growth is influenced by differing amounts of surface oxygen is a major step toward improved high-quality graphene films at industrial scale.

The team’s method “is a fundamental breakthrough, which will lead to growth of high-quality and large area graphene film,” said Sanjay Banerjee, who heads the Cockrell School’s South West Academy of Nanoelectronics (SWAN). “By increasing the single-crystal domain sizes, the electronic transport properties will be dramatically improved and lead to new applications in flexible electronics.”

Graphene has always been grown in a polycrystalline form, that is, it is composed of many crystals that are joined together with irregular chemical bonding at the boundaries between crystals (“grain boundaries”), something like a patch-work quilt. Large single-crystal graphene is of great interest because the grain boundaries in polycrystalline material have defects, and eliminating such defects makes for a better material.

“In the long run it might be possible to achieve meter-length single crystals,” Ruoff said. “This has been possible with other materials, such as silicon and quartz. Even a centimeter crystal size — if the grain boundaries are not too defective — is extremely significant.”

“We can start to think of this material’s potential use in airplanes and in other structural applications — if it proves to be exceptionally strong at length scales like parts of an airplane wing, and so on,” he said.

Another major finding by the team was that the “carrier mobility” of electrons (how fast the electrons move) in graphene films grown in the presence of surface oxygen is exceptionally high. This is important because the speed at which the charge carriers move is important for many electronic devices — the higher the speed, the faster the device can perform.

Yufeng Hao says he thinks the knowledge gained in this study could prove useful to industry.

“The high quality of the graphene grown by our method will likely be developed further by industry, and that will eventually allow devices to be faster and more efficient,” Hao said.

Single-crystal films can also be used for the evaluation and development of new types of devices that call for a larger scale than could be achieved before, added Colombo.

“At this time, there are no other reported techniques that can provide high quality transferrable films,” Colombo said. “The material we were able to grow will be much more uniform in its properties than a polycrystalline film.”

The Role of Surface Oxygen in the Growth of Large Single-Crystal Graphene on Copper

The growth of high-quality single crystals of graphene by chemical vapor deposition on copper (Cu) has not always achieved control over domain size and morphology, and the results vary from lab to lab under presumably similar growth conditions. We discovered that oxygen (O) on the Cu surface substantially decreased the graphene nucleation density by passivating Cu surface active sites. Control of surface O enabled repeatable growth of centimeter-scale single-crystal graphene domains. Oxygen also accelerated graphene domain growth and shifted the growth kinetics from edge-attachment–limited to diffusion-limited. Correspondingly, the compact graphene domain shapes became dendritic. The electrical quality of the graphene films was equivalent to that of mechanically exfoliated graphene, in spite of being grown in the presence of O.

24 pages of supplemental material

If you liked this article, please give it a quick review on ycombinator or StumbleUpon. Thanks

About The Author