Multiferroic heroics put instant-on computing in sight

If data could instead be encoded without current – for example, by an electric field applied across an insulator – it would require much less energy, and make things like low-power, instant-on computing a ubiquitous reality.

Cornell researchers have made a breakthrough in that direction with a room-temperature magnetoelectric memory device. Equivalent to one computer bit, it exhibits the holy grail of next-generation nonvolatile memory: magnetic switchability, in two steps, with nothing but an electric field.

A conceptual illustration of magnetization reversal, given by the compasses, with an electric field (blue) applied across the gold capacitors. The compass needles under the electric field are rotated 180 degrees from those not under the field (0 degrees rotated). The two-step switching sequence described in the paper is represented by the blurred compass needle under the electric field, making an intermediate state between the 0 and 180-degree rotated states. via John Herron

Nature – Deterministic switching of ferromagnetism at room temperature using an electric field

“The advantage here is low energy consumption,” Heron said. “It requires a low voltage, without current, to switch it. Devices that use currents consume more energy and dissipate a significant amount of that energy in the form of heat. That is what’s heating up your computer and draining your batteries.”

The researchers made their device out of a compound called bismuth ferrite, a favorite among materials mavens for a spectacularly rare trait: It’s both magnetic – like a fridge magnet, it has its own, permanent local magnetic field – and also ferroelectric, meaning it’s always electrically polarized, and that polarization can be switched by applying an electric field. Such so-called ferroic materials are typically one or the other, rarely both, as the mechanisms that drive the two phenomena usually fight each other.

This combination makes it a “multiferroic” material, a class of compounds that has enjoyed a buzz over the last decade or so. Paper co-author Ramamoorthy Ramesh, Heron’s Ph.D. adviser at University of California, Berkeley, first showed in 2003 that bismuth ferrite can be grown as extremely thin films and can exhibit enhanced properties compared to bulk counterparts, igniting its relevance for next-generation electronics.

Because it’s multiferroic, bismuth ferrite can be used for nonvolatile memory devices with relatively simple geometries. The best part is it works at room temperature; other scientists, including Schlom’s group, have demonstrated similar results with competing materials, but at unimaginably cold temperatures, like 4 Kelvin (-452 Fahrenheit) – not exactly primed for industry. “The physics has been exciting, but the practicality has been absent,” Schlom said.

A key breakthrough by this team was theorizing, and experimentally realizing, the kinetics of the switching in the bismuth ferrite device. They found that the switching happens in two distinct steps. One-step switching wouldn’t have worked, and for that reason theorists had previously thought what they have achieved was impossible, Schlom said. But since the switching occurs in two steps, bismuth ferrite is technologically relevant.

The multiferroic device also seems to require an order of magnitude lower energy than its chief competitor, a phenomenon called spin transfer torque, which Ralph also studies, and that harnesses different physics for magnetic switching. Spin transfer torque is already used commercially but in only limited applications.

They have some work to do; for one thing they made just a single device, and computer memory involves billions of arrays of such devices. They need to ramp up its durability, too. But for now, proving the concept is a major leap in the right direction.

“Ever since multiferroics came back to life around 2000, achieving electrical control of magnetism at room temperature has been the goal,” Schlom said.

Nature – Materials science: Two steps for a magnetoelectric switch

Magnetoelectric materials allow magnetism to be controlled by an electric field. The discovery of an indirect path for switching electrical polarization in one such material brings this idea close to practical use.

Abstract – Deterministic switching of ferromagnetism at room temperature using an electric field

The technological appeal of multiferroics is the ability to control magnetism with electric field. For devices to be useful, such control must be achieved at room temperature. The only single-phase multiferroic material exhibiting unambiguous magnetoelectric coupling at room temperature is BiFeO3. Its weak ferromagnetism arises from the canting of the antiferromagnetically aligned spins by the Dzyaloshinskii–Moriya (DM) interaction. Prior theory considered the symmetry of the thermodynamic ground state and concluded that direct 180-degree switching of the DM vector by the ferroelectric polarization was forbidden. Instead, we examined the kinetics of the switching process, something not considered previously in theoretical work. Here we show a deterministic reversal of the DM vector and canted moment using an electric field at room temperature. First-principles calculations reveal that the switching kinetics favors a two-step switching process. In each step the DM vector and polarization are coupled and 180-degree deterministic switching of magnetization hence becomes possible, in agreement with experimental observation. We exploit this switching to demonstrate energy-efficient control of a spin-valve device at room temperature. The energy per unit area required is approximately an order of magnitude less than that needed for spin-transfer torque switching. Given that the DM interaction is fundamental to single-phase multiferroics and magnetoelectrics our results suggest ways to engineer magnetoelectric switching and tailor technologically pertinent functionality for nanometre-scale, low-energy-consumption, non-volatile magnetoelectronics.

Magnetoelectric switching path.