Researchers from Moscow Institute of Physics and Technology (MIPT), Skolkovo Institute of Science and Technology (Skoltech), the Technological Institute for Superhard and Novel Carbon Materials (TISNCM), the National University of Science and Technology MISiS (Russia), and Rice University (USA) used computer simulations to find how thin a slab of salt has to be in order for it to break up into graphene-like layers. Based on the computer simulation, they derived the equation for the number of layers in a crystal that will produce ultrathin films with applications in nanoelectronics.
From 3D to 2D
Unique monoatomic thickness of graphene makes it an attractive and useful material. Its crystal lattice resembles a honeycombs, as the bonds between the constituent atoms form regular hexagons. Graphene is a single layer of a three-dimensional graphite crystal and its properties (as well as properties of any 2D crystal) are radically different from its 3D counterpart. Since the discovery of graphene, a large amount of research has been directed at new two-dimensional materials with intriguing properties. Ultrathin films have unusual properties that might be useful for applications such as nano- and microelectronics.
Previous theoretical studies suggested that films with a cubic structure and ionic bonding could spontaneously convert to a layered hexagonal graphitic structure in what is known as graphitisation. For some substances, this conversion has been experimentally observed. It was predicted that rock salt NaCl can be one of the compounds with graphitisation tendencies. Graphitisation of cubic compounds could produce new and promising structures for applications in nanoelectronics. However, no theory has been developed that would account for this process in the case of an arbitrary cubic compound and make predictions about its conversion into graphene-like salt layers.
SOURCE – Eurekalert
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