Rice University laboratory of materials scientist Pulickel Ajayan, in collaboration with NASA, has developed “fuzzy fibers” of silicon carbide that act like Velcro and stand up to the punishment that materials experience in aerospace applications.
The fibers strengthen composites used in advanced rocket engines that have to withstand temperatures up to 1,600 degrees Celsius (2,912 degrees Fahrenheit). Ceramic composites in rockets now being developed use silicon carbide fibers to strengthen the material, but they can crack or become brittle when exposed to oxygen.
The Rice lab embedded silicon carbide nanotubes and nanowires into the surface of NASA’s fibers. The exposed parts of the fibers are curly and act like the hooks and loops that make Velcro so valuable – but on the nanoscale.
The result, according to lead researchers Amelia Hart, a Rice graduate student, and Chandra Sekhar Tiwary, a Rice postdoctoral associate, creates very strong interlocking connections where the fibers tangle; this not only makes the composite less prone to cracking but also seals it to prevent oxygen from changing the fiber’s chemical composition.
Silicon carbide nanotubes attached to separate silicon carbide fibers, used by NASA, entangle each other in this electron microscope image. The material created at Rice University is intended for a ceramic composite that would make rocket engines stronger, lighter and better able to withstand extreme heat.
They grew their hooks and loops by first bathing silicon carbide fiber in an iron catalyst and then using water-assisted chemical vapor deposition, a process developed in part at Rice, to embed a carpet of carbon nanotubes directly into the surface. These become the template for the final product. The fibers were then heated in silicon nanopowder at high temperature, which converts the carbon nanotubes to silicon carbide “fuzz.”
The researchers hope their fuzzy fibers will upgrade the strong, light and heat-resistant silicon carbide fibers that, when put in ceramic composites, are being tested for robust nozzles and other parts in rocket engines. “The silicon carbide fiber they already use is stable to 1,600 C,” Tiwary said. “So we’re confident that attaching silicon carbide nanotubes and wires to add strength will make it even more cutting-edge.”
The new materials should also make entire turbo engines significantly lighter, Hart said. “Before they used silicon carbide composites, many engine parts were made of nickel superalloys that had to incorporate a cooling system, which added weight to the whole thing,” she said. “By switching to ceramic matrix composites, they could take out the cooling system and go to higher temperatures. Our material will allow the creation of larger, longer-lasting turbo jet engines that go to higher temperatures than ever before.”
Friction and compression testing showed the lateral force needed to move silicon carbide nanotubes and wires over each other was much greater than that needed to slide past either plain nanotubes or unenhanced fibers, the researchers reported. They were also able to easily bounce back from high compression applied with a nano-indenter, which showed their ability to resist breaking down for longer amounts of time.
Tests to see how well the fibers handled heat showed plain carbon nanotubes burning away from the fibers, but the silicon carbide nanotubes easily resisted temperatures of up to 1,000 C.
Hart said the next step will be to apply her conversion techniques to other carbon nanomaterials to create unique three-dimensional materials for additional applications.
The most recent and innovative silicon carbide (SiC) Fiber-SiC ceramic matrix composites, used for light-weight high-heat engine parts in aerospace applications, are woven, layered, then surrounded by a SiC ceramic matrix composite (CMC). To further improve both the mechanical properties and thermal and oxidative resistance abilities of this material, SiC nanotubes and nanowires (SiCNT/NWs) are grown on the surface of the SiC fiber via carbon nanotube conversion. This conversion utilizes the shape memory synthesis (SMS) method, starting with carbon nanotube (CNT) growth on the SiC fiber surface, to capitalize on the ease of dense surface morphology optimization and the ability to effectively engineer the CNT-SiC fiber interface to create a secure nanotube-fiber attachment. Then, by converting the CNTs to SiCNT/NWs, the relative morphology, advantageous mechanical properties, and secure connection of the initial CNT-SiC fiber architecture are retained, with the addition of high temperature and oxidation resistance. The resultant SiCNT/NW-SiC fiber can be used inside the SiC ceramic matrix composite for a high-heat turbo engine part with longer fatigue life and higher temperature resistance. The differing sides of the woven SiCNT/NWs act as the “hook and loop” mechanism of Velcro®, but in much smaller scale
Brian Wang is a Futurist Thought Leader and a popular Science blogger with 1 million readers per month. His blog Nextbigfuture.com is ranked #1 Science News Blog. It covers many disruptive technology and trends including Space, Robotics, Artificial Intelligence, Medicine, Anti-aging Biotechnology, and Nanotechnology.
Known for identifying cutting edge technologies, he is currently a Co-Founder of a startup and fundraiser for high potential early-stage companies. He is the Head of Research for Allocations for deep technology investments and an Angel Investor at Space Angels.
A frequent speaker at corporations, he has been a TEDx speaker, a Singularity University speaker and guest at numerous interviews for radio and podcasts. He is open to public speaking and advising engagements.