Singapore researchers have a new generalized method of producing anode materials for lithium-ion batteries. The anodes are made from metal oxide nanosheets, which are ultrathin, two-dimensional materials with excellent electrochemical and mechanical properties. This will enable more durable and longer lasting lithium-ion batteries.
These nanosheets (image on right) are 50,000 times thinner than a sheet of paper, allowing faster charging of power compared to current battery technology. The wide surface area of the nanosheets makes better contact with the electrolyte, thus increasing the storage capacity. The material is also highly durable and does not break easily, which improves the battery shelf life. Existing methods of making metal oxide nanosheets are time-consuming and difficult to scale up.
The IBN researchers came up with a simpler and faster way to synthesize metal oxide nanosheets using graphene oxide. Graphene oxide is a 2D carbon material with chemical reactivity that facilities the growth of metal oxides on its surface.
Graphene oxide was used as the template to grow metal oxides into nanosheet structures via a simple mixing process, followed by heat treatment. The researchers were able to synthesize a wide variety of metal oxides as nanosheets, with control over the composition and properties.
The new technique takes one day to produce the nanosheets, compared to one week for previously reported methods. It does not require the use of a pressure chamber and has just two steps in the synthesis process, making the nanosheets easy to manufacture on a large scale.
Tests showed that the nanosheets produced using this generalized approach have excellent lithium-ion battery anode performance, with some materials lasting three times longer than graphite anodes used in current batteries.
Abstract
Metal oxide nanosheets have attracted great attention in various fields, such as energy storage, catalysis, and sensors. Current synthesis methods of metal oxide nanosheets are laborious and not scalable. Herein, a facile and scalable method for the synthesis of metal oxide nanosheets is presented, which requires neither hydro-/solvothermal conditions nor postsynthesis template removal. The synthesis is versatile, as evidenced by the wide variety of metal oxide nanosheets derived. Nanosheet properties such as crystallinity, crystallite size, and carbon content can be controlled by tuning the synthesis conditions. The metal oxide nanosheets demonstrate promising performance as Li-ion battery anodes.
“Our nanosheets have shown great promise for use as lithium-ion anodes. This new method could be the next step toward the development of metal oxide nanosheets for high performance lithium-ion batteries. It can also be used to advance other applications in energy storage, catalysis and sensors,” said Prof Ying.
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