Imagine a future in which solar cells are all around us — on windows and walls, cell phones, laptops, and more. A new flexible, transparent solar cell developed at MIT is bringing that future one step closer.
The organic solar cell can be deposited on any kind of surface, rigid or flexible, transparent or not. The researchers are now working to improve the 4% efficiency of their graphene-based organic solar cells without sacrificing transparency. (Increasing the amount of active area would push up the PCE, but transparency would drop.) According to their calculations, the maximum theoretical PCE achievable at their current level of transparency is 10 percent. They’re also now considering how best to scale up their solar cells into the large-area devices needed to cover entire windows and walls, where they could efficiently generate power while remaining virtually invisible to the human eye.
The ability to deposit the solar cell on any surface makes it promising for use on consumer electronics — a field that’s growing rapidly worldwide. For example, solar cells could be fabricated directly on cell phones and laptops rather than made separately and then installed, a change that would significantly reduce manufacturing costs.
They would also be well-suited for future devices such as peel-and-stick solar cells and paper electronics. Since those devices would inevitably be bent and folded, the researchers subjected their samples to the same treatment. While all of their devices — including those with ITO electrodes — could be folded repeatedly, those with graphene electrodes could be bent far more tightly before their output started to decline.
The device combines low-cost organic (carbon-containing) materials with electrodes of graphene, a flexible, transparent material made from inexpensive and abundant carbon sources. This advance in solar technology was enabled by a novel method of depositing a one-atom-thick layer of graphene onto the solar cell — without damaging nearby sensitive organic materials. Until now, developers of transparent solar cells have typically relied on expensive, brittle electrodes that tend to crack when the device is flexed. The ability to use graphene instead is making possible truly flexible, low-cost, transparent solar cells that can turn virtually any surface into a source of electric power.
Photovoltaic solar cells made of organic compounds would offer a variety of advantages over today’s inorganic silicon solar cells. They would be cheaper and easier to manufacture. They would be lightweight and flexible rather than heavy, rigid, and fragile, and so would be easier to transport, including to remote regions with no central power grid. And they could be transparent. Many organic materials absorb the ultraviolet and infrared components of sunlight but transmit the visible part that our eyes can detect. Organic solar cells could therefore be mounted on surfaces all around us and harvest energy without our noticing them.
Researchers have made significant advances over the past decade toward developing transparent organic solar cells. But they’ve encountered one persistent stumbling block: finding suitable materials for the electrodes that carry current out of the cell.
A new flexible graphene solar cell developed at MIT is seen in the transparent region at the center of this sample. Around its edges are metal contacts on which probes can be attached during tests of device performance. Photo: Stuart Darsch
The most widely used current option is indium tin oxide (ITO). ITO is conductive and transparent, but it’s also stiff and brittle, so when the organic solar cell bends, the ITO electrode tends to crack and lift off. In addition, indium is expensive and relatively rare.
A promising alternative to ITO is graphene, a form of carbon that occurs in one-atom-thick sheets and has remarkable characteristics. It’s highly conductive, flexible, robust, and transparent; and it’s made from inexpensive and ubiquitous carbon. In addition, a graphene electrode can be just 1 nanometer thick — a fraction as thick as an ITO electrode and a far better match for the thin organic solar cell itself.
Two key problems have slowed the wholesale adoption of graphene electrodes. The first problem is depositing the graphene electrodes onto the solar cell. Most solar cells are built on substrates such as glass or plastic. The bottom graphene electrode is deposited directly on that substrate — a task that can be achieved by processes involving water, solvents, and heat. The other layers are then added, ending with the top graphene electrode. But putting that top electrode onto the surface of the so-called hole transport layer (HTL) is tricky.
The second problem with using graphene is that the two electrodes need to play different roles. The ease with which a given material lets go of electrons is a set property called its work function. But in the solar cell, just one of the electrodes should let electrons flow out easily. As a result, having both electrodes made out of graphene would require changing the work function of one of them so the electrons would know which way to go — and changing the work function of any material is not straightforward.
A smooth graphene transfer
For the past three years, Kong and Song have been working to solve these problems. They first developed and optimized a process for laying down the bottom electrode on their substrate.
In that process, they grow a sheet of graphene on copper foil. They then transfer it onto the substrate using a technique demonstrated by Kong and her colleagues in 2008. They deposit a layer of polymer on top of the graphene sheet to support it and then use an acidic solution to etch the copper foil off the back, ending up with a graphene-polymer stack that they transfer to water for rinsing. They then simply scoop up the floating graphene-polymer stack with the substrate and remove the polymer layer using heat or an acetone rinse. The result: a graphene electrode resting on the substrate.
But scooping the top electrode out of water isn’t feasible. So they instead turn the floating graphene-polymer stack into a kind of stamp, by pressing a half-millimeter-thick frame of silicon rubber onto it. Grasping the frame with tweezers, they lift the stack out, dry it off, and set it down on top of the HTL. Then, with minimal warming, they can peel off the silicon rubber stamp and the polymer support layer, leaving the graphene deposited on the HTL.
The current densities (or CDs, the amount of current flowing per unit area) and power conversion efficiencies (or PCEs, the fraction of incoming solar power converted to electricity) for the new flexible graphene/graphene devices and the standard rigid ITO/graphene devices were comparable. They were lower than those of the devices with one aluminum electrode, but that was a finding they expected.
“An aluminum electrode on the bottom will reflect some of the incoming light back into the solar cell, so the device overall can absorb more of the sun’s energy than a transparent device can,” says Kong.
The PCEs for all their graphene/graphene devices — on rigid glass substrates as well as flexible substrates — ranged from 2.8 percent to 4.1 percent. While those values are well below the PCEs of existing commercial solar panels, they’re a significant improvement over PCEs achieved in prior work involving semitransparent devices with all-graphene electrodes, the researchers say.
Measurements of the transparency of their graphene/graphene devices yielded further encouraging results. The human eye can detect light at wavelengths between about 400 nanometers and 700 nanometers. The all-graphene devices showed optical transmittance of 61 percent across the whole visible regime and up to 69 percent at 550 nanometers. “Those values [for transmittance] are among the highest for transparent solar cells with comparable power conversion efficiencies in the literature,” says Kong.
Portable electronic devices have become increasingly widespread. Because these devices cannot always be tethered to a central grid, powering them will require low-cost energy harvesting technologies. As a response to this anticipated demand, this study demonstrates transparent organic solar cells fabricated on flexible substrates, including plastic and paper, using graphene as both the anode and cathode. Optical transmittance of up to 69% at 550 nm is achieved by combining the highly transparent graphene electrodes with organic polymers that primarily absorb in the near-IR and near-UV regimes. To address the challenge of transferring graphene onto organic layers as the top electrode, this study develops a room temperature dry-transfer technique using ethylene-vinyl-acetate as an adhesion-promoting interlayer. The power conversion efficiency achieved for flexible devices with graphene anode and cathode devices is 2.8%–3.8% at for optical transmittance of 54%–61% across the visible regime. These results demonstrate the versatility of graphene in optoelectronic applications and it is important step toward developing a practical power source for distributed wireless electrical systems.