Mass production of new class of carbon nanotube semiconductors is close

University of Waterloo chemists have found a way to simultaneously control the orientation and select the size of single-walled carbon nanotubes deposited on a surface. That means the developers of semiconductors can use carbon as opposed to silicon, which will reduce the size and increase the speed of the devices while improving their battery life.

“We’re reaching the limits of what’s physically possible with silicon-based devices,” said co-author Derek Schipper, Canada Research Chair Organic Material Synthesis at the University of Waterloo. “Not only would single-walled carbon nanotube-based electronics be more powerful, they would also consume less power.”

The process, called the Alignment Relay Technique, relies on liquid crystals to pass orientation information to a metal-oxide surface. Small molecules called iptycenes then bond to the surface locking the orientation pattern into place. Their structure includes a small pocket large enough to fit a certain size carbon nanotube that remains after washing.

“This is the first time chemists have been able to externally control the orientation of small molecules covalently bonded to a surface,” said Schipper, a professor of chemistry and a member of the Waterloo Institute for Nanotechnology. “We’re not the first ones to come up with potential solutions to work with carbon nanotubes. But this is the only one that tackles both orientation and purity challenges at the same time.”

Schipper further pointed out that the approach is from the bottom up with the use of organic chemistry to design and build a molecule which then does the hard work.

“Once you’ve built the pieces, the process is simple. It’s a bench-top method requiring no special equipment,” Schipper explained.

In contrast to self-assembly techniques which rely on the design of a suitable molecule to fit snuggly together, this process can be controlled at every step, including the size of the iptycene “pocket”. In addition, this is the first a solution has been found to tackling the challenge of aligning and purifying carbon nanotubes at the same time.

Angewandte Chemie International Edition – Orientation Control of Molecularly Functionalized Surfaces Applied to the Simultaneous Alignment and Sorting of Carbon Nanotubes.

Abstract
Self-assembly has been relied upon for molecular alignment in many advanced technological applications. However, although effective, it is inherently limited in its capability for optimization. Despite the potential benefits, the seemingly fundamental strategy of external orientation control has yet to be realized. Herein we demonstrate an approach that allows control of the orientation of small molecules covalently bound to a surface. The method exploits an alignment relay technique, passing alignment information through a liquid-crystal medium to small molecules to control surface functionalization events. The method is technically simple and can be carried out on a bench top without the need for specialized equipment. Moreover, we demonstrate the utility of the resulting surfaces to address two long-standing problems in nanoscience: the sorting and alignment of single-walled carbon nanotubes. This new method enabled significant alignment of the nanotubes as well as length and diameter sorting.

15 pages of supplemental information.

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