Progress to Magnesium ion battery which theoretically could double lithium ion battery energy density

The race is on around the world as scientists strive to develop a new generation of batteries that can perform beyond the limits of the current lithium-ion based battery.

Researchers at the University of Illinois at Chicago have taken a significant step toward the development of a battery that could outperform the lithium-ion technology used in electric cars such as the Chevy Volt.

They have shown they can replace the lithium ions, each of which carries a single positive charge, with magnesium ions, which have a plus-two charge, in battery-like chemical reactions, using an electrode with a structure like those in many of today’s devices.

“Because magnesium is an ion that carries two positive charges, every time we introduce a magnesium ion in the structure of the battery material we can move twice as many electrons,” says Jordi Cabana, UIC assistant professor of chemistry and principal investigator on the study.

Advanced Materials – Direct Observation of Reversible Magnesium Ion Intercalation into a Spinel Oxide Host

Every battery consists of a positive and negative electrode and an electrolyte. The electrodes exchange electrons and ions, which are usually of positive charge. Only the ions flow through the electrolyte, which is an electric insulator so as to force the electrons to flow through the external circuit to power the vehicle or device.

To recharge the battery, the exchange is reversed. But the chemical reaction is not perfectly efficient, which limits how many times the battery can be recharged.

“The more times you can do this back and forth, the more times you will be able to recharge your battery and still get the use of it between charges,” Cabana said. “In our case, we want to maximize the number of electrons moved per ion, because ions distort the structure of the electrode material when they go in or leave. The more the structure is distorted, the greater the energy cost of moving the ions back, the harder it becomes to recharge the battery.”

“Like a parking garage, there are only so many spaces for the cars,” Cabana said. “But you can put a car in each space with more people inside without distorting the structure.”

Having established that magnesium can be reversibly inserted into electrode material’s structure brings us one step closer to a prototype, said Cabana.


Direct evidence of Mg2+ intercalation into a spinel-type Mn2O4 is provided. By com­bining tools with different sensitivities, from atomic resolution X-ray spectro­scopy to bulk X-ray diffraction, it is demonstrated that Mg2+ reversibly occupies the tetrahedral sites of the spinel structure through the reduction of Mn when the electrochemical reaction is performed.

SOURCES – University of Illinois at Chicago, Advanced Materials

“It’s not a battery yet, it’s a piece of a battery, but with the same reaction you would find in the final device,” said Cabana.